若想分离憐酸烯醇式丙酮酸羧化酶，应该选择下列哪种材料？

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SQL Error: select id,body,options from ***_enewstiku where sourceid='30527' and id < 2465176 and id<>'2465176' order by id desc limit 5 SQL Error: select id,body,options from ***_enewstiku where sourceid='30527' and id > 2465176 and id<>'2465176' order by id asc limit 5